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Electric Circuit Modeling of Lithium-Sulfur Batteries during Discharging State

机译:放电状态下锂硫电池的电路建模

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摘要

Lithium-ion batteries are characterized by having very good performance in terms of efficiency, lifetime, and selfdischarge, which allowed them to become the major player in the electric vehicle applications. However, they were not able to totally overcome the EV range anxiety. Thus, research is carried out nowadays to develop batteries with even higher gravimetric energy density, which should allow a substantial range increase. One of the technologies, which should be able to meet the range requirements is the Lithium-Sulfur (Li-S) battery. Thanks to the extensive research and development efforts, these cells are close to enter the market, being evaluate in various projects. In this paper, we have proposed an electrical circuit model for a Li-S pouch cell, which was parameterized based on extensive electrochemical impedance spectroscopy measurements. The developed model was verified using static and pulse discharge profiles, showing a good accuracy in predicting the voltage of the tested Li-S battery cell.
机译:锂离子电池的特点是在效率,寿命和自放电方面具有非常好的性能,这使其成为电动汽车应用中的主要参与者。但是,他们无法完全克服EV范围的焦虑。因此,如今正在进行研究以开发具有甚至更高的重量能量密度的电池,这应该允许范围的实质性增加。锂硫(Li-S)电池是应该能够满足范围要求的一项技术。由于广泛的研发工作,这些电池已接近进入市场,正在各种项目中进行评估。在本文中,我们提出了锂硫袋电池的电路模型,该模型基于广泛的电化学阻抗谱测量参数化。使用静态和脉冲放电曲线对开发的模型进行了验证,显示了预测被测Li-S电池单元电压的良好准确性。

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